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Gutterman Reaction ?
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A Gutter man reaction is a chemical reaction
in which aromatic compounds are formylated by a mixture of hydrogen cyanide and hydrogen chloride in the presence of a Lewis acid catalyst such as AlCl3.
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The Gattermann reaction, (also known as the Gattermann formylation and the Gattermann salicylaldehyde synthesis) is a chemical reaction in which aromatic compounds are formylated by a mixture of hydrogen cyanide (HCN) and hydrogen chloride (HCl) in the presence of a Lewis acid catalyst such as AlCl3. It is named for the German chemist Ludwig Gattermann and is similar to the Friedel–Crafts reaction.
The reaction can be simplified by replacing the HCN/AlCl3 combination with zinc cyanide. Although it is also highly toxic, Zn(CN)2 is a solid, making it safer to work with than gaseous HCN.The Zn(CN)2 reacts with the HCl to form the key HCN reactant and Zn(CN)2 that serves as the Lewis-acid catalyst in-situ. An example of the Zn(CN)2 method is the synthesis of mesitaldehyde from mesitylene.
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