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No they are not perpendicular
cause if it's perpendicular then the light would diffused.
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PROOF IN 2 nd pic
The polarization angle ( also called Brewster's angle)is defined as the angle of incidence at which light with a particular polarization is perfectly transmitted through a transparent dielectric surface, with no reflection.
Brewster's Law states that the tangent of the angle of polarization is numerically equal to the refractive index of the medium
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