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"if any poison expires then its became more poisonous are less ...?"
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Answers
Poison are just chemicals, and time affects them in the same way other chemicals change over time. And don't get too hung up on expiration dates, either: they're just guesses given the wide range of storage conditions.
"if any poison expires then its became more poisonous are less ...?"
It could be more toxic; it could be less. It could be differently toxic, so that it's no longer as effective against its target but could cause severe harm to other species. It only means that one chemical may have started to degrade, and the end product of that degradation could be very different.
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They become less poisonous, meaning you need a bigger dose, but you'd have to wait years after the expiration before it stopped working altogether. Some organic poisons have an expiry date for exactly the opposite reason.The inorganic poisons like arsenic or mercury compounds tend not to break down as such.