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Answer:Chemical Kinetics
Step-by-step explanation:
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Answer:
(a) Initial rate of a first order reaction =kC
=1×10
−2
×1.0=1×10
−2
mol L
−1
s
−1
(b) Concentration after 60 seconds is calculated by applying first order kinetic equation,
k=
60
2.303
log
10
(1−x)
1
or 1×10
−2
=
60
2.303
[−log(1−x)]
or
2.303
60×10
−2
=−log(1−x)=0.2605
log(1−x)=−0.2605=
1
ˉ
.7395
(1−x)= antilog of (
1
ˉ
.7395)=0.5489 mol L
−1
Rate of reaction after 1 minute =k×C
=1×10
−2
×0.5489
=5.489×10
−3
mol L
−1
s
−1
Step-by-step explanation:
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