hlw guys what is antifluorite structure ❤
Answers
Antifluorite structure is derived from fluorite structure by inter-changing the positions of positive and negative ions in the lattice. For example, CaF
2
has fluorite structure. The Ca
2+
ions are arranged in ccp arrangement and the F
−
ions occupy all the tetrahderal holes. Li
2
O has antifluorite structure. The O
2−
ions are arranged in ccp arrangement and the Li
+
ions occupy all the tetrahederal holes.
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antifluorite structure :
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The antifluorite structure has ccplfcc anions with cations in all (T+ and T-) tetrahedral sites. The difference between antifluorite and fluorite is that anti- fluorite refers to an anion array with tetrahedral cations, whereas fluorite has the inverse arrangement with a ccp cation array and tetrahedral anions.
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