Question

How activation enrgy influence processes of adsorption?

Answer 1

How could and do microwaves influence chemistry at interfaces?

Wm Curtis Conner, Geoffrey A Tompsett

The Journal of Physical Chemistry B 112 (7), 2110-2118, 2008

Many chemical reactions may be accelerated by order(s) of magnitude when exposed to microwaves. Reaction selectivities are often enhanced. Reasons for microwave reaction enhancements are speculative, often conflicting. We have demonstrated that microwaves can change the energies and/or the “effective temperature” of individual species at interfaces. Changes in the relative energies of reacting species or intermediates are shown by Monte Carlo simulation to lead to the observed enhancements in reaction rates or selectivities....

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