How are the following conversions carried out? (i) Propene → Propan-2-ol (ii) Benzyl chloride → Benzyl alcohol (iii) Ethyl magnesium chloride → Propan-1-ol. (iv) Methyl magnesium bromide → 2-Methylpropan-2-ol.
Answers
(i) Propene → Propan-2-ol
If propene is reacted with water in the presence of an acid as a catalyst, then propan-2-ol is produced.
(ii) Benzyl chloride → Benzyl alcohol
If benzyl chloride is treated with NaOH followed by acidification then benzyl alcohol is obtained.
(iii) Ethyl magnesium chloride → Propan-1-ol.
When ethyl magnesium chloride is reacted with methanal, on hydrolysis gives propan-1-ol.
(iv) Methyl magnesium bromide → 2-Methylpropan-2-ol.
When methyl magnesium bromide is reacted with propane, on hydrolysis gives 2-methyl propane-2-ol.
The reactions of the following are in the attachment below.
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Some more questions :
1 Name the reagents used in the following reactions:
(i) Oxidation of a primary alcohol to carboxylic acid.
(ii) Oxidation of a primary alcohol to aldehyde.
(iii) Bromination of phenol to 2,4,6-tribromophenol.
(iv) Benzyl alcohol to benzoic acid.
(v) Dehydration of propan-2-ol to propene.
(vi) Butan-2-one to butan-2-ol.
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Explain the following with an example
i Kolbe's reaction
ii) Reimer- Tiemann reaction
iii) Williamson ether synthesis
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