how can u detect Cu2+ radical by chemical test (with reaction)?
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The group reagent for identifying a Cu⁺² cation is "dilute HCl + H₂S"
It gives a black precipitate of copper sulphide (CuS).
dil. HCl +
Cu⁺² --------------------> CuS (black precipitate)
H₂S
Cu⁺² can also be identified in the following reactions.
on long standing
1)Cu⁺² + NaOH -------------> Cu(OH)₂ ----------------------------> CuO
(pale blue) (black ppt)
excess NH₄OH
2)Cu⁺² + NH4OH -----------> Cu(OH)₂ -------------------------> [Cu(NH₃)₄]⁺²
(deep blue)
3)Cu⁺² + K₄[Fe(CN)₆] ----------------------> CuK₂[Fe(CN)₆]
(chocolate brown ppt)
:)
It gives a black precipitate of copper sulphide (CuS).
dil. HCl +
Cu⁺² --------------------> CuS (black precipitate)
H₂S
Cu⁺² can also be identified in the following reactions.
on long standing
1)Cu⁺² + NaOH -------------> Cu(OH)₂ ----------------------------> CuO
(pale blue) (black ppt)
excess NH₄OH
2)Cu⁺² + NH4OH -----------> Cu(OH)₂ -------------------------> [Cu(NH₃)₄]⁺²
(deep blue)
3)Cu⁺² + K₄[Fe(CN)₆] ----------------------> CuK₂[Fe(CN)₆]
(chocolate brown ppt)
:)
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