how can we know that the silver is only the best conductor why iron is not the best conductor
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Silver is the best conductor of electricity because it contains a higher number of movable atoms (free electrons). For a material to be a good conductor, the electricity passed through it must be able to move the electrons; the more free electrons in a metal, the greater its conductivity
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As to why silver is the best conductor, the answer is that its electrons are freer to move than those of the other elements. This has to do with its valence and crystal structure.
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