How can you find an element is a atom or ion ?
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Atoms are neutral; they contain the same number of protons as electrons. By definition, an ion is an electrically charged particle produced by either removing electrons from a neutral atom to give a positive ion or adding electrons to a neutral atom to give a negative ion.
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A particular atom will have the same number of protons and electrons and most atoms have at least as many neutrons as protons. An element is a substance that is made entirely from one type of atom. For example, the element hydrogen is made from atoms containing just one proton and one electron.
I'm little confused in your question . did you mean to ask about finding electronic configuration of an atom of an element.
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