how can you justify that though q and w are not state function seat q + w is a state function
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This is total energy called internal energy E = q+w. It is a state function as it depends on the intial and final state and independent of the path. The entropy of steam is more than that of water at its boiling point. ... At the boiling point, both water and steam (water vapours) exist together and are in equilibrium.
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