How come the monomers of terylene and PET the same
Answers
Explanation:
Dacron and Terylene are two trade names for the synthetic fibers produced from poly(ethylene terephtalate) (PET). PET is the most important polyester manufactured from condensation polymerization of terephtalic acid (or its diesters) and ethylene glycol. Thus, the answer is yes, they are the same material
Answer:
POLYESTERS
This page looks at the formation, structure and uses of a common polyester sometimes known as Terylene if it is used as a fibre, or PET if it used in, for example, plastic drinks bottles.
Poly(ethylene terephthalate)
What is a polyester?
A polyester is a polymer (a chain of repeating units) where the individual units are held together by ester linkages.
The diagram shows a very small bit of the polymer chain and looks pretty complicated. But it isn't very difficult to work out - and that's the best thing to do: work it out, not try to remember it. You will see how to do that in a moment.
The usual name of this common polyester is poly(ethylene terephthalate). The everyday name depends on whether it is being used as a fibre or as a material for making things like bottles for soft drinks.
When it is being used as a fibre to make clothes, it is often just called polyester. It may sometimes be known by a brand name like Terylene.
When it is being used to make bottles, for example, it is usually called PET.
Making polyesters as an example of condensation polymerisation
In condensation polymerisation, when the monomers join together a small molecule gets lost. That's different from addition polymerisation which produces polymers like poly(ethene) - in that case, nothing is lost when the monomers join together.
A polyester is made by a reaction involving an acid with two -COOH groups, and an alcohol with two -OH groups.
In the common polyester drawn above:
The acid is benzene-1,4-dicarboxylic acid (old name: terephthalic acid).
The alcohol is ethane-1,2-diol (old name: ethylene glycol).
Now imagine lining these up alternately and making esters with each acid group and each alcohol group, losing a molecule of water every time an ester linkage is made.
That would produce the chain shown above (although this time written without separating out the carbon-oxygen double bond - write it whichever way you like).
Note: This does NOT describe the way the actual reaction happens - it is a way of working out the structure of the polymer. The chemistry of the reaction is more complicated than this.
The diagram shows a slightly shorter bit of chain than the corresponding one at the top of the page. However, it is exactly consistent with the loss of water from the last diagram. It was impossible to include another ethane-1,2-diol in that diagram for space reasons. If any of this offends you, draw it again yourself so that everything matches! In fact, it would be good practice to draw a bit of chain starting from a few more monomers.
This is what I meant further up the page by working the structure out rather than remembering it. The structures of both monomers are easy to remember. If you line them up and remove water as I have shown, the structure follows automatically.
Hydrolysis of polyesters
Simple esters are easily hydrolysed by reaction with dilute acids or alkalis.
Polyesters are attacked readily by alkalis, but much more slowly by dilute acids. Hydrolysis by water alone is so slow as to be completely unimportant. (You wouldn't expect your polyester fleece to fall to pieces if you went out in the rain!)
If you spill dilute alkali on a fabric made from polyester, the ester linkages are broken. Ethane-1,2-diol is formed together with the salt of the carboxylic acid.
Because you produce small molecules rather than the original polymer, the fibres are destroyed, and you end up with a hole!
For example, if you react the polyester with sodium hydroxide solution: