Question

How did we understand whether the valence electron has spun up or spun down?

Answer 1

As we can see, in one orbital, the orientation of the two electrons is always the opposite of each other. One electron will be spin up, and the other electron is spin down. If the last electron that enters is spin up, then ms = +1/2. If the last electron that enters is spin down, then the ms = -1/2