How do you account for the following observations ? (3)
(a) Though alkaline potassium permanganate and acidic potassium
permanganate both are used as oxidants, yet in the
manufacture of benzoic acid from toluene we use alcoholic
potassium permanganate as an oxidant. Why? Write a balanced
redox equation for the reaction.
(b) When concentrated sulphuric acid is added to an inorganic
mixture containing chloride, we get colourless pungent smelling
gas HCI, but if the mixture contains bromide then we get red
vapour of bromine. Why? Write the balanced chemical
equation.
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Explanation:
Though alkaline potassium permanganate and acidic potassium permanganate both are used as oxidants, yet in the manufacture of benzoic acid from toluene we use alcoholic potassium permanganate as an oxidant.
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