how do you calculate the formula mass and empirical formula of C3H8 (molecular formula)
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Nomenclature, a collection of rules for naming things, is important in science and in many other situations. This module describes an approach that is used to name simple ionic and molecular compounds, such as NaCl, CaCO3, and N2O4. The simplest of these are binary compounds, those containing only two elements, but we will also consider how to name ionic compounds containing polyatomic ions, and one specific, very important class of compounds known as acids(subsequent chapters in this text will focus on these compounds in great detail). We will limit our attention here to inorganic compounds, compounds that are composed principally of elements other than carbon, and will follow the nomenclature guidelines proposed by IUPAC. The rules for organic compounds, in which carbon is the principle element, will be treated in a later chapter on organic chemistry.
Ionic Compounds
To name an inorganic compound, we need to consider the answers to several questions. First, is the compound ionic or molecular? If the compound is ionic, does the metal form ions of only one type (fixed charge) or more than one type (variable charge)? Are the ions monatomic or polyatomic? If the compound is molecular, does it contain hydrogen? If so, does it also contain oxygen? From the answers we derive, we place the compound in an appropriate category and then name it accordingly.
Compounds Containing Only Monatomic Ions
The name of a binary compound containing monatomic ions consists of the name of the cation (the name of the metal) followed by the name of the anion (the name of the nonmetallic element with its ending replaced by the suffix –ide). Some examples are given in Table 7.
NaCl, sodium chlorideNa2O, sodium oxideKBr, potassium bromideCdS, cadmium sulfideCaI2, calcium iodideMg3N2, magnesium nitrideCsF, cesium fluorideCa3P2, calcium phosphideLiCl, lithium chlorideAl4C3, aluminum carbideTable 7. Names of Some Ionic Compounds
Compounds Containing Polyatomic Ions
Compounds containing polyatomic ions are named similarly to those containing only monatomic ions, except there is no need to change to an –ide ending, since the suffix is already present in the name of the anion. Examples are shown in Table 8.
KC2H3O2, potassium acetate(NH4)Cl, ammonium chlorideNaHCO3, sodium bicarbonateCaSO4, calcium sulfateAl2(CO3)3, aluminum carbonateMg3(PO4)2, magnesium phosphateTable 8. Names of Some Polyatomic Ionic Compounds
Ionic Compounds in Your Cabinets
Every day you encounter and use a large number of ionic compounds. Some of these compounds, where they are found, and what they are used for are listed in Table 9. Look at the label or ingredients list on the various products that you use during the next few days, and see if you run into any of those in this table, or find other ionic compounds that you could now name or write as a formula.
–ic and –ous to designate metals with higher and lower charges, respectively: Iron(III) chloride, FeCl3, was previously called ferric chloride, and iron(II) chloride, FeCl2, was known as ferrous chloride. Though this naming convention has been largely abandoned by the scientific community, it remains in use by some segments of industry. For example, you may see the words stannous fluoride on a tube of toothpaste. This represents the formula SnF2, which is more properly named tin(II) fluoride. The other fluoride of tin is SnF4, which was previously called stannic fluoride but is nonopentafluorideN2O4dinitrpter). Typical oxyacids consist of hydrogen combined with a polyatomic, oxygen-containing ion. To name oxyacids:
Omit “hydrogen”
Start with the root name of the anion
Replace –ate with –ic, or –ite with –ous
Add “acid”
For example, consider H2CO3 (which you might be tempted to call “hydrogen carbonate”). To name this correctly, “hydrogen” is omitted; the –ate of carbonate is replace with –ic; and acid is added—so its name is carbonic acid. Other examples are given in Table 14. There are some exceptions to the general naming method (e.g., H2SO4 is called sulfuric acid, not sulfic acid, and H2SO3 is sulfurous, not sulfous, acid).
FormulaAnion NameAcid NameHC2H3O2acetateacetic acidHNO3nitratenitric acidHNO2nitritenitrous .
Ionic Compounds
To name an inorganic compound, we need to consider the answers to several questions. First, is the compound ionic or molecular? If the compound is ionic, does the metal form ions of only one type (fixed charge) or more than one type (variable charge)? Are the ions monatomic or polyatomic? If the compound is molecular, does it contain hydrogen? If so, does it also contain oxygen? From the answers we derive, we place the compound in an appropriate category and then name it accordingly.
Compounds Containing Only Monatomic Ions
The name of a binary compound containing monatomic ions consists of the name of the cation (the name of the metal) followed by the name of the anion (the name of the nonmetallic element with its ending replaced by the suffix –ide). Some examples are given in Table 7.
NaCl, sodium chlorideNa2O, sodium oxideKBr, potassium bromideCdS, cadmium sulfideCaI2, calcium iodideMg3N2, magnesium nitrideCsF, cesium fluorideCa3P2, calcium phosphideLiCl, lithium chlorideAl4C3, aluminum carbideTable 7. Names of Some Ionic Compounds
Compounds Containing Polyatomic Ions
Compounds containing polyatomic ions are named similarly to those containing only monatomic ions, except there is no need to change to an –ide ending, since the suffix is already present in the name of the anion. Examples are shown in Table 8.
KC2H3O2, potassium acetate(NH4)Cl, ammonium chlorideNaHCO3, sodium bicarbonateCaSO4, calcium sulfateAl2(CO3)3, aluminum carbonateMg3(PO4)2, magnesium phosphateTable 8. Names of Some Polyatomic Ionic Compounds
Ionic Compounds in Your Cabinets
Every day you encounter and use a large number of ionic compounds. Some of these compounds, where they are found, and what they are used for are listed in Table 9. Look at the label or ingredients list on the various products that you use during the next few days, and see if you run into any of those in this table, or find other ionic compounds that you could now name or write as a formula.
–ic and –ous to designate metals with higher and lower charges, respectively: Iron(III) chloride, FeCl3, was previously called ferric chloride, and iron(II) chloride, FeCl2, was known as ferrous chloride. Though this naming convention has been largely abandoned by the scientific community, it remains in use by some segments of industry. For example, you may see the words stannous fluoride on a tube of toothpaste. This represents the formula SnF2, which is more properly named tin(II) fluoride. The other fluoride of tin is SnF4, which was previously called stannic fluoride but is nonopentafluorideN2O4dinitrpter). Typical oxyacids consist of hydrogen combined with a polyatomic, oxygen-containing ion. To name oxyacids:
Omit “hydrogen”
Start with the root name of the anion
Replace –ate with –ic, or –ite with –ous
Add “acid”
For example, consider H2CO3 (which you might be tempted to call “hydrogen carbonate”). To name this correctly, “hydrogen” is omitted; the –ate of carbonate is replace with –ic; and acid is added—so its name is carbonic acid. Other examples are given in Table 14. There are some exceptions to the general naming method (e.g., H2SO4 is called sulfuric acid, not sulfic acid, and H2SO3 is sulfurous, not sulfous, acid).
FormulaAnion NameAcid NameHC2H3O2acetateacetic acidHNO3nitratenitric acidHNO2nitritenitrous .
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