Question

• How do you explain the solubility of ammonia in water and chloroform ? Which is more ?

Answer 1

Answer:

As expected on the basis of this analysis, ammonia is more soluble (same pressure and temperature) in chloroform than in carbon tetrachloride, where no hydrogen-bonded complex can be formed

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Answer 2

Answer:

Both are polar solvents, so I imagine ammonia dissolves in both, though I do not know facts about ammonia solution in chloroform. Ammonia NH3 dissolves in water accepting an H+ from H2O to leave behind OH-, whence this solution is often called ammonium hydroxide. But in fact only a small portion of the NH3 molecules so accept an H+ ion -- the fraction might be very roughly in the range from 0.01% to 1 %, depending on the amount of NH3 which is dissolved (and perhaps drastically on whether there are other ions already present, especially H+(aq) or OH- ions). I am guessing there is very little to no ion formation for NH3 dissolved in chloroform, CHCl3 -- the H in chloroform is not really acidic.

Explanation: