How do you prove average kinetic energy of molecules is directly proportional to the absolute temperature
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Kinetic Molecular Theory states that gas particles are in constant motion and exhibit perfectly elastic collisions. The average kinetic energy of a collection of gas particles is directly proportional to absolute temperature only.
The following is the deduction of kinetic theory in terms of pressure:
p=mnv23
Where,
m is the mass of the gas molecule
n is the number of molecules per unit volume
v is the rms speed
So, n = NV
Where N is the number of molecules
Substituting for n we get,
pV=mNv23
mv22=E is the kinetic energy of the molecule
Therefore, pV=2NE3
From the ideal gas equation,
pV=μRT
Where μ=NNA
μRT=2NE3
NRTNA=2NE3
E=3kT/2
Where,
k=RNA
Therefore, it can be said that kinetic energy is proportional to temperature.
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