How many grams of carbon-di-oxide gas will be produced when 16.8 grams of 90% magnesium carbonate reacts with excess hydrochloric acid? [ Mg -24u, C-12u, O-16u]
Answers
Answer:
We can calculate the percentage composition by dividing the mass of a component by the total mass of the mixture. Then the ratio is to be multiplied by 100. It is also called the mass percent.
Complete step by step solution:
- We will write the reaction first:
CaCO3+2HCl→CaCl2+H2O
Here, we will consider the moles of calcium carbonate as X mole and hydrochloric acid as 2x.
MgCO3+2HCl→MgCl2+H2O
Here, we will consider moles of magnesium carbonate as Y mole and hydrochloric acid as 2y.
Now, we can write
N1V1−N2V21000
where, N1
= Number of moles of HCl
V1
= Volume of HCl
N2
= Number of moles of NaOH
V2
= Volume of NaOH
By putting all values in above equation, we get:
2x+2y=(0.8×50−0.25×16)10002x+2y=(40−4)10002x+2y=3610002x+2y=0.036x+y=0.0362x+y=0.018
Consider this equation as equation 1,
Now, we will find the molecular weight of calcium carbonate:
CaCO3=40+12+3×16=40+12+48=40+60=100
Now, we will find the molecular weight of magnesium carbonate:
MgCO3=24+12+3×16=24+12+48=24+60=84
We can write:
x×100+y×84=1.64
Consider this equation as equation 2
- From equation 1 and 2 we can find the value of x as:
from equation 1 we can write: x + y =0.018
so, y = x + 0.018
Now substitute the value of y in equation 2:
100(x)+84(0.018−x)=1.64100x+1.512−84x=1.64100x−84x+1.512=1.6416x=1.64−1.51216x=0.128x=0.12816x=0.008
Now, we will write the percentage of calcium carbonate as:
Weight of calcium carbonate x =0.008 gm
%ofCaCO=x×molecular weight1.64×100
=0.008×1001.64×100
=0.81.64×100
=0.4878×100
=48.78
Now, we will write the percentage of magnesium carbonate as:
100 - percentage of calcium carbonate
= 100- 48.78
=51.22%