How many water molecules are coordinated to fe3+ ion in feh2o6.Cl3 complex?
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COMPLEX METAL IONS - THE ACIDITY OF THE HEXAAQUA IONS
This page explains why complex ions of the type [M(H2O)6]n+ are acidic.
The general explanation
A closer look at the distribution of charge in the ion
The pH's of solutions containing hexaaqua ions vary a lot from one metal to another (assuming you are comparing solutions of equal concentrations). However, the underlying explanation is the same for all of them.
We'll take the hexaaquairon(III) ion, [Fe(H2O)6]3+ as typical. The structure of the ion is:
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