how R and S configuration is determined in stereochemistry
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Stereocenters are labeled R or S
The "right hand" and "left hand" nomenclature is used to name the enantiomers of a chiral compound. ... If the arrow points in a counterclockwise direction ( left when leaving the 12 o' clock position), the configuration at stereocenter is considered S ("Sinister" → Latin= "left").
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