how the convertion of an aldehyde to acetal can carry out right chemical equation?
Answers
Answer:
It has been demonstrated that water adds rapidly to the carbonyl function of aldehydes and ketones to form geminal-diol. In a similar reaction alcohols add reversibly to aldehydes and ketones to form hemiacetals (hemi, Greek, half). This reaction can continue by adding another alcohol to form an acetal
Explanation: How will you bring out the following conversion :
(i) Acetyl chloride to acetaldehyde :
Rosemond's reaction:
H 2gas is passed through a boiling solution of acetyl chloride in xylene in the presence of P d catalyst supported by BaSO4.The catalyst is poisoned by Sulphur or quinoline. This avoids further reduction of acetaldehyde to ethyl alcohol CH3 − O∣∣C −Cl Pd/BaSO4 Sulphur CH3 − O∣∣C −H + H Cl
(ii) Methanol to Ethanal.
Methanol reacts with methyl magnesium bromide followed by acid hydrolysis to form ethanol. Controlled oxidation gives ethanal