Chemistry, asked by gurleen3818, 1 year ago

How to calculate excited energy of hydrogen?

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Answered by preetghotra
5
According to the theory quantum mechanics, an electron bound to an atom can not have any value of energy, rather it can only occupy certain states which correspond to certain energy levels. The formula defining the energy levels of a Hydrogen atom are given by the equation: E = -E0/n2, where E0 = 13.6 eV (1 eV = 1.602×10-19 Joules) and n = 1,2,3… and so on. The energy is expressed as a negative number because it takes that much energy to unbind (ionize) the electron from the nucleus. It is common convention to say an unbound electron has zero (binding) energy. Because an electron bound to an atom can only have certain energies the electron can only absorb photons of certain energies exactly matched to the energy difference, or “quantum leap”, between two energy states.

Because an electron bound to an atom can only have certain energies the electron can onlyabsorb photons of certain energies.

When an electron absorbs a photon it gains the energy of the photon. Because an electron bound to an atom can only have certain energies the electron can only absorb photons of certain energies. For example an electron in the ground state has an energy of -13.6 eV. The second energy level is -3.4 eV. Thus it would take E2 − E1 = -3.4 eV − -13.6 eV = 10.2 eV to excite the electron from the ground state to the first excited state.

If a photon has more energy than the binding energy of the electron then the photon will free the electron from the atom – ionizing it. The ground state is the most bound state and therefore takes the most energy to ionize.

Emitting Photons – Rydberg Formula

When an electron drops from a higher level to a lower level it sheds the excess energy, a positive amount, by emitting a photon.

Generally speaking, the excited state is not the most stable state of an atom. An electron has a certain probability to spontaneously drop from one excited state to a lower (i.e. more negative) energy level. When an electron drops from a higher level to a lower level it sheds the excess energy, a positive amount, by emitting a photon.

The energy of the emitted photon is given by the Rydberg Formula. This formula is essentially the subtraction of two energ

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