how to calculate the energy needed to ionise 46(g) of Na(g)
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We have to calculate the energy needed to ionise 46g of Na (g).
solution : Ionisation Energy is the amount of energy required to remove an electron from its isolated ground state.
so we have to find energy needed to form Na to Na⁺ ion.
from Bohr's theory,
Ionisation Energy = 13.6 × Z² eV/atom
from sodium, Z = 11
no of atoms of sodium in 46 g = mass of sodium/atomic mass of sodium × Avogadro's number
= 46g/23g × 6.023 × 10²³
= 12.046 × 10²³ atoms
now ionisation Energy of Na = 13.6 × 11² × 12.046 × 10²³ eV
we know, 1 eV = 1.6 × 10^-19 J
so, ionisation Energy of Na = 13.6 × 121 × 12.046 × 10²³ × 1.6 × 10^-19 J
= 31,716.6362 × 10⁴ J
= 3.17166362 × 10^7 J
≈ 3.17 × 10^7 J
Therefore energy needed to ionise 46 g of Na is 3.17 × 10^7 J.