How to distinguish between Cnv and Cnh point group
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It is an S6 (S2n) axis that is coincident with the C3 axis. An S6 rotation is a combination of a C6 followed by a perpendicular reflection (i.e., a σh).
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The difference between Cnv and Cnh point groups is that Cnv contains but Cnh contains planes.
- Cnv point groups contain one principal axis of symmetry denoted by Cn. It also contains n number of vertical planes of symmetry or which is parallel to the Cn axis. It does not contain n number of C2.
- Cnh point groups contain one principal axis of symmetry denoted by Cn. It also contains one horizontal plane of symmetry or which is perpendicular to the Cn axis. It does not contain n number of C2.
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