How to obtain acetone hydrogen by acetone
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H + CH3COH3 --> H2 + CH3COH2
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The reaction of hydrogen atoms with acetone vapor has been investigated by means of the Wood‐Bonhoeffer technique at room temperature. The sole reaction products under these conditions are methane and carbon monoxide. A deuterium exchange experiment showed that the methane product is almost completely deuterized, while undecomposed acetone is exchanged to the extent of 4.1 atom percent. A reaction series has been devised which satisfactorily explains the experimental facts. The activation energy of 9 kcal. found for the over‐all process has been assigned to the proposed initiatory step:
H+CH3COCH3→H2+CH3COCH2
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