Chemistry, asked by zopemeenal9705, 1 year ago

How to say if a azeotrope is minimum boiling or maximum boiling?

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Answered by Harshii47
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There are two types of solutions, one is Ideal Solutions which follows the Raoult's law and the other is Non Ideal Solutions which doesn't follows the Raoult's. Within non-ideal solutions, some solutions show positive deviation, in which the intermolecular force of attraction between the solute-solute and solvent-solvent are more stronger than solute-solvent interaction and others show negative deviation, in which the intermolecular force of attraction between the solute-solute and solvent-solvent are weaker than solute-solvent interaction.
 Non ideal binary solution of two liquids showing Positive Deviation are known as Minimum Boiling Azeotrope.
For example a binary solution of ethanol and water is consider a Minimum Boiling Azeotrope and those Non Ideal solutions which show 
Negative Deviation are known as Maximum Boiling Azeotropes
For example a mixture of water and nitric acid is consider a Maximum Boiling Azeotrope.
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