How will you convert aniline into phenol and p-aminoazobenzene????
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★ Aniline to phenol -
Aniline is first treated with HCl/NaNO2 to form benzene diazonium chloride.
C6H5-NH2 + HCl ⇒ C6H5-N2Cl
Benzene diazoium chloride on warming with water yields phenol.
C6H5-N2Cl + H2O ⇒ C6H5-OH + N2 + HCl
★ Aniline to p-aminoazobenzene -
Aniline is first treated with HCl/NaNO2 to form benzene diazonium chloride.
C6H5-NH2 + HCl ⇒ C6H5-N2Cl
Benzyl diazonium chloride again reacts with aniline ti form p-aminoazobenzene.
C6H5-N2Cl + C6H5-NH2 ⇒ C6H5-NH-C6H5 + N2 + HCl
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