How will you convert butyl bromide to pentan-1-ol?
Answers
through grignard reaction
Explanation:
CH3CH2CH2CH2Br + Mg (anhydrous ether) = CH3CH2CH2CH2MgBr -------+HCHO + anhydrous ether------> CH3CH2CH2CH2CH2OMgBr -------acid medium------> CH3CH2CH2CH2CH2OH
Answer:
Halogen atoms are substituted for one or more hydrogen atoms in an alkane to form alkyl halides, also known as haloalkanes ( fluorine, chlorine, bromine, or iodine ).
Explanation:
Butyl bromide on reaction with magnesium in dry ether results in the formation of butyl magnesium bromide (CH₃CH₂CH₂CH₂-MgBr) i.e., a Grignard reagent.
Butyl magnesium bromide on reaction with formaldehyde (HCHO) results in the formation of a tetrahedral intermediate {CH₃CH₂CH₂CH₂CH₂(OMgBr)}.
The tetrahedral intermediate upon the aqueous workup results in the formation of an alcohol i.e., 1-pentanol or pentan-1-ol (CH₃CH₂CH₂CH₂CH₂OH).
The reactions are as shown below.
CH₃CH₂CH₂CH₂Br + Mg(in dry ether) → CH₃CH₂CH₂CH₂-MgBr
CH₃CH₂CH₂CH₂-MgBr + HCHO → CH₃CH₂CH₂CH₂CH₂(OMgBr)
CH₃CH₂CH₂CH₂CH₂(OMgBr) + H₃O⁺ → CH₃CH₂CH₂CH₂CH₂OH + H₂O
Hence, the conversion of butyl bromide to pentan-1-ol is shown above.
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