How will you distinguish between:
(a) Ethyl chloride and ethyl bromide
(b) Chlorobenzene and cyclohexyl chloride.
(c) Vinyl chloride and ethyl chloride.
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Ethyl bromide and Ethyl chloride can be distinguished by silver nitrate test. On addition of silver nitrate in ethyl chloride, white precipitate is formed which is soluble in NH
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B:The dipole moment of chlorobenzene is less than cyclo hexyl chloride as in chloro benzene C-Cl bond is sp2 hybridised where as in cyclohexyl chloride the C_cl bond is Sp3 Hybridised . as sp2 has more s character and more electronegative than sp3. Chlorobenzene is less polar than cyclohexyl chloride.
C:Ethyl chloride and vinyl chloride will be distinguished by bromine water . Vinyl chloride will react with bromine water and it will become decolorised. Ethyl chloride will not decolourise bromine water
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