How will you extract a metal carbonate is the metal is placed in the middle order of the reactivity series?
Answers
Extracting metals in the middle of Reactivity series -
* These metals occur in the form of Sulfides or Carbonates
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* Extracting a Metal in carbonate form -
Eg :- Zinc carbonate ( ZnCO3 ).
(we know that a metal is easy to obtain when it is in it's metal oxide form.
So we first convert our metal carbonate into metal oxide through a process called calcination .)
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Calcination :- Heating a metal strongly in absence of oxygen
ZnCO3 ----> ZnO + Co2
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(now we have the metal oxide ( ZnO ) which can be reduced to metal by using reducing agents.)
ZnO + C ----> Zn + CO
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Therefore, the pure metal is obtained.
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Question: How will you extract a metal carbonate if the metal is placed in the middle order of the reactivity series?
Explanation:
Activity series of metals:
The metals arranged in a series of their reactivity from highest to lowest .
Middle element of the activity series are as:
For Ex : Zn, Fe, Al ,etc
Now, to Extract a middle order metal (of activity series) from its carbonate form.
For Example: FeCO3 ( Siderite)
Though we can extract Fe from its ore by many methods , but the best way to extract it easily is by converting it into its Oxide(Metal Oxide)which can be done through Calcination.
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Calcination: In this process , the concentrated ore is heated in a limited supply of air below its Melting point.
Importance of Calcination:
- Moisture is removed
- Volatile impurities is removed; ore becomes porous.
- Carbonate ore decomposed into respective oxides and lose CO2.
Equation:
FeCO3 -----> FeO(iron 2 oxide) + CO2
Now, the calcined ore is mixed with suitable quantity of coke or charcoal and is heated to a high temperature.
Equation:[carbon-reduction process]
2FeO + C -----> 2Fe + CO2
[ Thus , we can also add some Flux to obtain a pure metal ]
Flux + impurities-----> Slag (solid)
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Hope it helps
Thank you!