How will you prepare carbolic acid from cumene?
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Answer:
Cumene (isopropylbenzene) is oxidised in the presence of air to cumene hydroperoxide. It is converted to phenol and acetone by treating it with dilute acid.
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Answer:
Carbolic acid, which is also known as phenol, can be prepared from cumene using the cumene hydroperoxide process.
Here are the steps involved:
- Cumene is oxidized with air or oxygen to form cumene hydroperoxide. This reaction is typically carried out in the presence of a catalyst such as molybdenum or tungsten.
- The cumene hydroperoxide is then cleaved by acid to form phenol and acetone. The reaction usually takes place with an acid catalyst present, like sulfuric acid or phosphoric acid.
- The phenol and acetone are then separated by distillation, with phenol being the more volatile compound and therefore boiling off first.
- Overall, the process can be summarized by the following equation:
Cumene + Oxygen → Cumene Hydroperoxide
Cumene Hydroperoxide + Acid → Phenol + Acetone
- It's worth noting that the cumene hydroperoxide process is one of the most common methods for producing phenol on an industrial scale.
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