Hydrogen halides, having highest melting point and highest boiling point are respectively
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This attraction is stronger than London dispersion forces hence the presence of a hydrogen bond significantly raises the boiling point of the compound. Hence, HF has the highest boiling point amongst the four compounds.
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Explanation:
The hydrogen halides are colourless gases at standard conditions for temperature and pressure (STP) except for hydrogen fluoride, which boils at 19 °C. Alone of the hydrogen halides, hydrogen fluoride exhibits hydrogen bonding between molecules, and therefore has the highest melting and boiling points of the HX series
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