Identify the compound which can exhibit cis-trans isomerism (A) 1,1-dichloro cyclobutane (B) 1,3-pentadiene (C) 2-chloro 1,1-dimethyl cyclo propane (D) Malonic acid
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Answer:
a-dichloro cyclobutane (B)
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Answer:
1,3-pentadiene can exhibit cis-trans isomerism
Explanation:
- Geometrical isomerism, or cis and transforms, is observed in compounds with each doubly bonded carbon attached to two different groups (such as Cab=Cab, Cab=Ccd). The restricted rotation of the double bond causes geometrical isomerism.
- Despite the fact that triple bonds have limited rotation, alkynes do not exhibit geometrical isomerism because the triply bonded carbons are only attached to one group each.
- Alkenes and cyclic compounds can exhibit cis-trans isomerism.
1,3-pentadiene, with two isomers:
- cis-1,3-pentadiene.
- trans-1,3-pentadiene, or piperylene.
Maleic acid is the cis isomer of butenedioic acid.
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