If e fe2+/fe is x1 and e fe3+/fe is x2 then fe3+/fe2+ will be
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Answer:
E+Fe+/Fe2+=2x1+3x2
Step-by-step explanation:
The EMF of E+Fe2+/Fe=x1
The EMF of E+Fe3+/Fe=x2
We have to find E+F+/Fe3+ =?
Let E+F+/Fe3+=z
The half reaction of E+Fe2+/Fe is given by
Fe2++2e−→Fe
Gibbs free energy of cell =−nEF
ΔG+=−2Fx1 …… (1)
The half reaction of E+Fe3+/Fe is given by
Fe3++3e−→Fe
ΔG+=−3Fx2 ……. (2)
The half reaction for EFe+/Fe3+ A
Fe+−e−→Fe2+
ΔG+=−(nFz)
=−Fz ….. (3)
Adding equation (1) & (2) and comparing with (3)
=−Fz=−2Fx1+(−3x1)
=−Fz=−F[2x1+3x2]
z=2x4+3x2
∴E+Fe+/Fe2+=2x1+3x2 .
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