if excluded volume is taken zero compressibility factor Z is
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vander valls equation is
(p+a/v2)(v-b) = RT
if excluded volume is 0 then correction term in volume means 'b' is 0 ...
now , eq becomes
(p + a/v2)v = RT
pv + a/v = RT
pv/RT + a/vRT = 1
z + a/vRT = 1
z = 1 - a/vRT
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