Chemistry, asked by svibhu963, 9 months ago

If one mole of an ideal monoatomic gas undergoes
a reversible cyclic process as given in volume
versus temperature graph. Volume is taken in litre
and temperature is taken in kelvin.
V (litre)
С
16
V. T = constant
8
B
А
1000K
→ T(K)
500
It is found that the magnitude of work done by the
gas in complete process i.e. during entire cycle is
XR (where Rishiwersal gas constant The value
X
of
to nearest integer is (use In2 = 0.7)
5​

Answers

Answered by syedrehan46249
1

Answer:

Correct option is A)

Clockwise cyclic process

a) Work done by gas

W = area(△ABC)

=

2

1

(2V

o

−V

o

)(3P

o

−P

o

)

=P

o

V

o

b) n = 1 monoatomic gas

C

V

=

2

3

R⇒

R

C

V

=

2

3

C

P

=

2

5

R⇒

R

C

P

=

2

5

Heat rejected by gas in the path CA

CA → It is isochoric

CA

=

2

5

(P

o

V

o

−2P

o

V

o

)=

2

−5

(P

o

V

o

−2P

o

V

o

)

Heat absorbed by the gas in path AB

AB → isochoric

∴dθ

AB

=C

V

dT

=C

V

(T

final

−T

initial

)

=C

V

(

R

P

f

V

f

R

P

i

V

i

)

=

R

C

V

(P

f

V

f

−P

i

V

i

)

=

2

3

(P

f

V

f

−P

i

V

i

)

=

2

3

(3P

o

V

o

−P

o

V

o

)=3P

o

V

o

c) Total heat absorbed during the process

dθ=dθ

AB

+dθ

BC

+dθ

CA

=3P

o

V

o

+dθ

BC

+(

2

−5

P

o

V

o

)

dθ=

2

P

o

V

o

+dθ

BC

Change in internal energy

dU=0

⇒dθ=dW(dθ=dU+dW)

2

P

o

V

o

+dθ

BC

=P

o

V

o

BC

=

2

P

o

V

o

d) PV equation for the process BC is

P=−mV+C (max temperature will be between B and C)

here

m=

V

o

2P

o

,C=5P

o

∴P=−(

V

o

2P

o

)V+5P

o

PV=−(

V

o

2P

o

)V

2

+5P

o

V

RT=−(

V

o

2P

o

)V

2

+5P

o

V[PV=RT;forn=1]

T=

R

1

[5P

o

V−(

V

o

2P

o

)V

2

]

dV

dT

=T

⇒5P

o

V

o

4P

o

V=0⇒V=

4

5V

o

at,V=

4

5V

o

;T=maximum

T

max

=

R

1

5P

o

(

4

5V

o

)−(

V

o

2P

o

)(

4

5V

o

)

2

T

max

=

8

25

R

P

o

V

o

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