If the solubility product of agbro3 and ag2so4 are 5.5*10^-5 and 2*10^-5 respectively the relationship between the solubility
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The relationship between the solubility of Ag₂SO₄ and AgBrO₃ is given as s'³ = 11 s²
where s' = solubility of Ag₂SO₄
and s = solubility of AgBrO₃
- The dissociation of AgBrO₃ can be represented as:
AgBrO₃⇔ Ag⁺ + BrO₃⁻
So, K = s × s
K = s²
-The dissociation of Ag₂SO₄ can be represented as:
Ag₂SO₄ ⇔ 2Ag⁺ + SO₄²⁻
So, K' = (2s')² × s'
K' = 4s'³
- thus, K'/K = 4s'³/s²
⇒ 5.5 × 10⁻⁵/ 2 × 10⁻⁵ = 4s'³/s²
⇒ s'³/s² = (4 × 5.5)/2
⇒ s'³/s² = 22/2
⇒ s'³/s² = 11
⇒ s'³ = 11 s²
- This is the required relation
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