Question

If there is no temperature difference across material is more then the thermal conductivity is less or more

Answer 1

Walking on bathroom tile in winter is annoying since it feels so much colder than the carpet. This is interesting, since the carpet and tile are usually both at the same temperature (i.e. the temperature of the interior of the house). The different sensations we feel is explained by the fact that different materials transfer heat at different rates. Tile and stone conduct heat more rapidly than carpet and fabrics, so tile and stone feel colder in winter since they transfer heat out of your foot faster than the carpet does. 

Wait, I thought "coldness" was entering my body.

In general, good conductors of electricity (metals like copper, aluminum, gold, and silver) are also good heat conductors, whereas insulators of electricity (wood, plastic, and rubber) are poor heat conductors. The figure below shows molecules in two bodies at different temperatures. The (average) kinetic energy of a molecule in the hot body is higher than in the colder body. If two molecules collide, an energy transfer from the hot to the cold molecule occurs. The cumulative effect from all collisions results in a net flux of heat from the hot body to the colder body. We call this transfer of heat between two objects in contact thermal conduction.