If v1, v2, v3 and v4 are velocities of the electron present in the first orbit of H, He+, Li+2 and Be+3, then which of the following should be their increasing order? (a) v1 v3 > v2 > v1 (c) v1 v4 (d) v1 > v2 v4
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Answer:
V of H
2
⊕
=
nh
2πZe
2
or V α
n
Z
∴ V H
2
⊕
α 1 (Z = 1, n = 1)
V of Li
2+
α
3
3
α 1 (Z = 3, n = 3)
Therefore, velocity of e
−
in the third orbit of Li
2+
is the same velocity of an e
−
in the first orbit of H atom
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