If x,y and z are Mulliken electronegativity, ionization potential and electron-affinity respectively. Then the electron affinity (z) in the terms of electronegativity (x) and ionization potential (y) will be:
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2X-EA-IP=0
Electron affinity: The amount of energy released when an electron is added to the outermost shell of one mole of an isolated gaseous atom in its lower energy state.
Ionisation energy: Minimum energy required to remove most loosly held outer most shell e – in ground state from an isolated gaseous atom is known as ionisation potential.
X=
2
IP+EA
2X−IP−EA=0
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