(iii) Out of water, tert-butyl alcohol, propan-2-ol and ethyl alcohol, which is most acidic?
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Propan - 2 - ol
Follow SN-2 mechanism
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Out of water, tert-butyl alcohol, propan-2-ol and ethyl alcohol, water is most acidic.
- The acidity of a substance depends on the stability of the conjugate base formed.
- Higher the stability of its conjugate base (-OH in water and -OR in alcohols), greater will be the acidic nature.
- -OH ion is more stable than -OR ion due to higher inductive effect in the latter.
- Thus water is more acidic than alcohols.
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