In a compoiu carbon and nitorgen are present in a ratio 3:1 by mass. Find out the molecular formula of the compound.(Atomic mass of C= 12u and Atomic mass of H=1 u).
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We have mass ratio of elements C : H: N = 9 :1 :3.5
Let us find the empirical formula of compound
Element
Atomic mass
Mass ratio
Relative number atoms
Simplest ratio
C
12
9
9/12 = 0.75
0.75 X4 = 3
H
1
1
1/1 = 1
1X4 = 4
N
14
3.5
3.5\14 = 0.25
0.25 X 4 = 1
Therefore, empirical fornula = C3H4N1
Now calculate the empirical formula mass= 3X 12 + 4X1 + 1 X 14 = 54
n = Molecular mass/ Empirical formula mass = 108/54 = 2
Moleclar formula = n X Empirical formula = 2 X C3H4N1
= C6H4N2
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