In a highly acidic solution the dominant form of glycine is
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In a highly basic solution, pH = 13, the dominant form of glycine is: NH2—CH3+—COO-. For amino acids with neutral R groups, at any pH below the pI of the amino acid, the population of amino acids in solution will have: a net positive charge.
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In a highly acidic solution the dominant form of the glycine will be the cationic form.
Explanation:
- Glycine is an amino acid. Amino acids are the compounds which contain both amino group (basic group) and carboxylic group (acidic group).
- The amino acids are present in the dipolar form within the same molecule is called 'zwitter ion'. It can be shown as ⁺NH₃-CHR-COO⁻.
- Zwitter ion is amphoteric in nature. In the aqueous solution of amino acids , they exist in equilibrium between the dipolar form, anionic form and cationic form.
⁺NH₃-CHR-COOH ⇄ ⁺NH₃-CHR-COO⁻ ⇄ ⁺NH₃-CHR-COO⁻
Cationic form Dipolar form Anionic form
- In the acidic solution the concentration of H⁺ ions will be greater. Therefore, they react with carboxylate group and cationic form of glycine will be dominated.
⁺NH₃-CH₂-COO⁻ + H⁺ ⁺NH₃-CH₂-COOH
Cationic form.
Therefore, the cationic form of glycine dominates in acidic solution.
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