In a particular reaction 2 kJ
of heat is released by the system and 6 kJ
of work is done on the system. Determine
of ∆H and ∆U?
Answers
Solution : According to the first law of
thermodynamics
∆U = Q + W
Q = -2 kJ, W = +6 kJ
∆U = -2 kJ + 6 kJ = + 4 kJ
Qp = ∆H = - 2kJ
The correct answer to the above question is given below -
Given: Heat released = 2 kJ
Work done on the system = 6 kJ
To find: Determine ΔH and ΔU
Solution:
According to the first law of thermodynamics - "Energy can neither be created nor be destroyed, it can only be transformed from one source of energy to another."
ΔU = Q + W (Where ΔU is the change in internal energy, Q is the heat energy absorbed and W is the amount of work done.)
Since heat is released, therefore, Q = -2 kJ, and Work is done on the system so W = +6 kJ
ΔU = -2 + 6
= 4 kJ
Since ΔH is the amount of heat absorbed or released by the system, therefore, ΔH will be equal to - 2kJ
ΔU = +4 kJ
ΔH = -2 kJ