Question

In a reaction of aniline a coloured product C was obtained.
The structure of C would be :

Answer 1

Explanation:

The answer is in attachment

Answer 2

The correct option is option B.

Explanation:

• The reactant is the annilene.

• When annilene is reacted with sodium nitrite in presence of hydrochloric acid, the salt formed is benzene diazonium chloride or BDC.

• This salt when reacts with dimethylbenzylammonia, the benzene diazonium chloride reacts with the reactant.

• As nitrogen is a electron rich species, its a ortho para directing group.

• This now directs the benzene diazonium chloride to para as steric hindrance is present in ortho.

• So salt of option B is formed.

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