In an experiment on the specific heat capacity of solid, a 200gm block of metal at 15°c is dropped in a copper calorimeter of mass 270 gm containing 150 cm3 of water at 27°c. The final temp. is 40°C, calculate the specific heat capacity of solid.
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Explanation:
☆Mass of the metal, m = 0.20 kg = 200 g
Initial temperature of the metal, T
1 = 150 oC
Final temperature of the metal, T 2= 40oC
Calorimeter has water equivalent of mass, m = 0.025 kg = 25 g
Volume of water, V = 150 cm3
Mass (M) of water at temperature T = 27
oC:150×1=150g
Fall in the temperature of the metal:ΔT
m=T
1 -T2
=150−40=110 oC
Specific heat of water, C w=4.186J/g/K
Specific heat of the metal =C
Heat lost by the metal, =mCT .... (i)
Rise in the temperature of the water and calorimeter system: T
1 −T=40−27=13 oC
Heat gained by the water and calorimeter system: =m1
C w T=(M+m)C w
..Heat lost by the metal = Heat gained by the water and colorimeter system
mCΔT ,m =(M+m)C
wT w 200×C×110=(150+25)×4.186×13
C=(175×4.186×13)/(110×200)=0.43Jg −1
k−1If some heat is lost to the surroundings, then the value of C will be smaller than the actual value.
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