In crystalline solid the atom A and B are arranged as follows :-
a) atom A are arranged in ccp array.
b) atom B occupied all octahedral void & tetrahedral void. What is the formula of compound?
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Let the number of atoms of A be N.
Number of octahedral voids is N.
Number of tetrahedral voids is 2N.
i) There will be one atom of B in the octahedral void.
ii) There will be one atom of B in the tetrahedral void ( 2/1 ×2N).
Total 2 atoms of B for each atom of A.
Therefore, the formula of the compound is
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