Chemistry, asked by mansoorfousiya7, 11 months ago

in hydrogen atom, the de Broglie wavelength of an electron in the second Bohr orbit is (given that Bohr radius,52.9pm)​

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Answered by gourimmanu
92

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Answered by abhi178
2

In hydrogen atom, the de Broglie wavelength of an electron in the second Bohr orbit is ..

According to Bohr's theory of atomic structure, " Angular momentum of an electron in an orbit is integral multiple of  \frac{h}{2\pi} ."

in mathematical form, \bf{mvr_n=\frac{nh}{2\pi}}

we know, linear momentum, P = mv

\bf{P=\frac{nh}{2\pi r_n}} ...(1)

According to De-Broglie's wavelength equation, " the wavelength of any particle is the ratio of Plank's constant to the momentum of that particle.

in mathematical form, \bf{\lambda=\frac{h}{P}} ...(2)

from equations (1) and (2) we get,

\bf{\lambda=\frac{2\pi r_n}{n}

now putting values of n and r₂

we know, \bf{r_n=52.9n^2} pm , for hydrogen atom.

so, r₂ = 52.9 × 4 = 211.6 pm

n = 2

so wavelength = \frac{2\pi (211.6pm)}{2} = 211.6π pm

Therefore De-Broglie's wavelength is 211.6π pm.

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