In hydrogen-like atom (z = 11), nth line of lyman series has wavelength equal to the de-broglies wavelength of electron in the level from which it originated. What is the value of n?
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1λ=Rz2(1n21−1n22)
1λ=R(11)2(11−1n2)
λ=hρ=hmv
λ=hrmvr=rh2πnh=2πrn.
λ=2πrn=(π(0.529×10−10)n2)(n)(11)
1λ=112π(0.529×10−10)n=11(2π)(0.529×10−10)n=1.1×107(11)2(1−1n2)
=12π(0.529×10−10)(1.1×102)(11)=n−1n
n−1n=25
n2−1=25 n
n2−25 n−1=0
n=25
Hence answer = 24
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