Chemistry, asked by pomes21065, 9 months ago

In N2 molecule, the atoms are bonded by One σ, Two One σ, One Two σ, One Three σ bonds

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Answered by saiyedmeenaz81
0

Answer:

Many of us are already aware of the definition of a sigma bond from our teachers, text books or from many of the websites online. However, if you are still not aware of what these two bonds are, then here is a basic definition of the two:

Sigma bond: A covalent bond resulting from the formation of a molecular orbital by the end-to-end overlap of atomic orbitals, denoted by the symbol σ.

Now have a look at this illustration to see how this end-to-end overlapping occures:

Fig 1: Formation of a Sigma bond

Misconception: many students in the Pacific may have this worng notion that a sigma

Pi bond: A covalent bond resulting from the formation of a molecular orbital by side-to-side overlap of atomic orbitals along a plane perpendicular to a line connecting the nuclei of the atoms, denoted by the symbol π.

Here's another illustration showing how the side-to-side overlapping occurs:

Fig 2: Formation of a Pi bond

It is important to note that different sources use different terms to define what a sigma and pi bond is. However, once examined carefully, it will be evident that they all try to explain the same thing.

Misconception: many students in the Pacific may have this wrong notion that a sigma bond is the result of the overlapping of s orbitals and a pi bond is the result of the overlapping of p orbitals because they may relate the 's' to 'sigma' and the 'p' to 'pi'. However, it is seen that sigma bonds can be formed by the overlapping of both the s and p orbitals and not just s orbital.

You may have noticed that in order to understand these definitions it is obvious that we must know what an s and p orbital is.

Please click here to learn more about Atomic Orbitals if you are unfamiliar with the concept.

Note: A single bond such as (C-H) has one sigma bond whereas a double (C=C) and triple (C≡C) bond has one sigma bond with remaining being pi bonds.

Bond type

No. of σ bond

No. of π bonds

Single (C-H)

1

0

Double (C=C)

1

1

Triple (C≡C)

1

2

Sigma (σ) Bonding:

To understand Sigma bonding let us look at the simple molecule of methane (CH4).

Methane, CH4

We may all be familiar with drawing methane using electron dot diagrams, which would look something like this:

Fig 3: Covalent bonding in Methane

Misconception: many students after drawing such electron dot diagrams fail to appreciate that in reality molecules exist as a 3D system and not as a two dimensional system as shown above. These diagrams are drawn for simplicity and should not be viewed as an exact representation of what a molecule looks like.

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